This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.
Beilstein J. Org. Chem. 2023, 19, 1452–1459, doi:10.3762/bjoc.19.104
Graphical Abstract
Scheme 1: The biosynthesis of 2-methylisoborneol (1). A) SAM-dependent methylation of GPP to 2-Me-GPP by GPPM...
Figure 1: The function of the N-terminal A domain of 2MIBS. A) Relative production of 1 with full length 2MIB...
Scheme 2: Enzymatic synthesis of analogs of 1. A) Preparation of 2 from DA-4 and IA-1, B) preparation of 3 an...
Beilstein J. Org. Chem. 2023, 19, 1386–1398, doi:10.3762/bjoc.19.100
Figure 1: Terpenes produced by characterised terpene synthases.
Figure 2: Phylogenetic tree constructed from the amino acid sequences of 4018 terpene synthase homologs. Blue...
Figure 3: A) Total ion chromatogram of the products obtained from FPP with KkdCS, B) EI mass spectrum of 10, ...
Figure 4: Total ion chromatograms of the products obtained from FPP A) with SlADS and B) with SsADS, C) EI ma...
Figure 5: Total ion chromatograms of the products obtained with NbEIZS A) from FPP and B) from GPP, and C) st...
Figure 6: Total ion chromatogram of the products obtained with SfES. Peak numbers refer to compound numbers i...
Scheme 1: A) Cope rearrangement of 24 and 26. B) Cyclisation mechanism from FPP to 23, identifying compound 26...
Figure 7: Total ion chromatograms of the products obtained with A) SsHS, B) ScHS, C) SfHS, and D) SmGAS. Peak...
Figure 8: A) Total ion chromatogram of the products obtained from GGPP with KkAS, B) EI mass spectrum of allo...
Beilstein J. Org. Chem. 2022, 18, 818–824, doi:10.3762/bjoc.18.82
Scheme 1: Biosynthesis of 2-MIB (1). A) Naturally observed pathway through methylation of GPP to 2-Me-GPP by ...
Figure 1: A) Active site of 2MIBS with the bound substrate surrogate 2FGPP (generated with Pymol from the cry...
Scheme 2: Synthesis of (R)- and (S)-2-Me-LPP.
Figure 2: Structures of 2MIBS side products and spontaneous degradation products of 2-Me-LPP. The enantiomers...
Figure 3: Total ion chromatograms of extracts from an incubation of A) enantiomerically pure (R)-2-Me-LPP wit...
Scheme 3: Hypothetical mechanism for the isomerization of (S)-2-Me-LPP through 2-Me-GPP to (R)-2-Me-LPP.